Crystal structure of tris[(4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane-κ8 N 2,O 6)rubidium] rubidium nonastannide
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چکیده
The crystal structure of the title compound, [Rb(C18H36N2O6)]3RbSn9, consists of deltahedral [Sn9]4- cluster anions, Rb+ cations and cryptand mol-ecules, which partially sequester the cations. Those cations, which are not coordinated by cryptand mol-ecules, are neighboured directly to the [Sn9]4- clusters and inter-connect them to form ∞1[RbSn9]3- chains. These chains extend parallel to [001] and are arranged in a pseudo-hexa-gonal rod packing, separated by the Rb-cryptand complex cations.
منابع مشابه
[Rb(18-crown-6)][Rb([2.2.2]-cryptand)]Rb2Sn9·5NH3
The crystal structure of the title compound, poly[[(4,7,13,16,21,24-hexa-oxa-1,10-diaza-bicyclo-[8.8.8]hexa-cosa-ne)rubidium] [[(1,4,7,10,13,16-hexa-oxacyclo-octa-deca-ne)rubidium]di-μ-rubidium-μ-nona-stannide] penta-ammonia], {[Rb(C(18)H(36)N(2)O(6))][Rb(3)Sn(9)(C(12)H(24)O(6))C(12)H(24)O(6))]·5NH(3)}(n) represents the first ammoniate of a Zintl anion together with two different chelating subs...
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